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Lesson: Chapter 10 — Chemical Bonds

10.4. Intermolecular bonds 1 of 2

Attraction between molecules

Every bond so far has been inside a molecule. Polarity creates a second kind of attraction, one that acts between molecules.

A water molecule has hydrogen atoms carrying a small positive charge and an oxygen atom carrying a small negative one. Put two water molecules next to each other and the hydrogen of one is attracted to the oxygen of the other, exactly as any opposite charges would be.

Intermolecular bond

An attraction arising between one molecule and another, rather than between the atoms within a molecule. Also called an intermolecular force.

Figure to be added

Several water molecules arranged so that the hydrogen atom of each is drawn towards the oxygen atom of a neighbour, with the intermolecular bonds marked (figure 10.20).

Weaker than the bonds inside

These attractions are real but modest. They are not as strong as the covalent bonds holding the oxygen and hydrogen atoms together within a single water molecule.

Attraction Acts between Strength
Covalent bond Atoms inside one molecule Strong
Intermolecular bond One molecule and the next Much weaker

That difference explains something you have seen. Boiling water turns liquid into steam without decomposing it into hydrogen and oxygen: the heat is enough to pull the molecules apart from one another, but nowhere near enough to break the bonds inside them.

Weak does not mean unimportant. These attractions are what decide whether a substance is a gas, a liquid or a solid at room temperature.