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Lesson: Chapter 14 — Hydrocarbons and their derivatives

Putting the chapter together 2 of 3

The exercise

Worked answers to the chapter's exercise.

Question 1 — LP gas

LP gas is a mixture of propane and butane

  1. Write the molecular formulas of propane and butane.
  2. Draw the structures of propane and butane.
  3. If burning these compounds gives only carbon dioxide (CO2) and water (H2O), write a balanced equation for each reaction.
  4. Is using LP gas as a fuel better for the environment than using firewood? Give your view.

The answer

(i) Propane C3H8; butane C4H10. (ii) The structures:

The structure of propane: a chain of three carbons joined by single bonds, with eight hydrogens.
The structure of butane: a chain of four carbons joined by single bonds, with ten hydrogens.

(iii) The balanced equations:

C3H8 + 5O2 → 3CO2 + 4H2O

2C4H10 + 13O2 → 8CO2 + 10H2O

propane; butane

(iv) LP gas or firewood

LP gas burns cleanly and completely in a stove, giving mainly carbon dioxide and water, with no smoke, soot or ash; it also gives more heat for its mass. Firewood burns less completely and gives smoke and soot that harm the lungs, and cutting trees for firewood destroys forests. Both give carbon dioxide, and LP gas is a fossil fuel that will not be replaced, so a fair view is that LP gas is cleaner to use, while wood from replanted trees is renewable.

Question 2 — petrol

Octane, the main alkane in petrol

  1. If petrol burns completely in an engine, what products can form?
  2. Name two harmful substances released into the environment when petrol burns incompletely.
  3. How would you know that the gas in a household LP gas cooker is burning incompletely?

The answer

  1. Carbon dioxide and water: 2C8H18 + 25O2 → 16CO2 + 18H2O.
  2. Carbon monoxide (CO), a poisonous gas, and soot (unburnt carbon).
  3. The flame turns yellow or orange instead of blue, it gives off smoke, and soot blackens the bottom of the pans.

Question 3 — polythene

A widely used synthetic polymer

  1. What is the chemical name of polythene?
  2. Draw the structure of the monomer polythene is made from, and name it.
  3. Give two advantages and two disadvantages of polythene.

The answer

  1. Polyethene.
  2. Ethene, C2H4, drawn below.
  3. Advantages: light, waterproof, lasts long, cheap. Disadvantages: does not biodegrade, so it pollutes; gives off poisonous gases when burned.
The structure of ethene: two carbons joined by a double bond, each with two hydrogens.

Question 4 — PVC water pipes

PVC pipes rather than iron

  1. Give three reasons why PVC pipes are better than iron pipes for water.
  2. What is the name of the monomer used to make PVC?
  3. Draw the structure of that monomer.

The answer

  1. PVC does not rust or corrode in water (iron does, as in chapter 12); it is much lighter and easier to cut, join and carry; it is cheaper; and it does not conduct electricity.
  2. Chloroethene (vinyl chloride).
  3. Drawn below.
The structure of chloroethene: ethene with one hydrogen replaced by chlorine.

Question 5 — natural polymers

Three natural polymers

  1. Name three natural polymers you know.

The answer

  1. Any three of: rubber, protein, starch, cellulose, DNA, RNA.

Question 1(iv) asks for an opinion and question 2(iii) for everyday experience, so their answers draw on the chapter and on grade 10 combustion; they are guides, not the only right answers.