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Lesson: Chapter 10 — Chemical Bonds

10.5. Properties of ionic and covalent compounds 1 of 3

Which solutions conduct

Whether a substance is held together by ionic or covalent bonds can be settled by an experiment that takes only a few minutes: see whether its solution conducts electricity.

Activity 03

Testing four solutions

You will need four beakers, two carbon rods, a bulb, two batteries, connecting wires and clips.

  • Label four identical beakers A, B, C and D.
  • Put common salt solution in A, copper sulfate solution in B, sugar solution in C and distilled water in D.
  • Stand the two carbon rods in each beaker in turn, complete the circuit, and note whether the bulb lights.
  • Wash the carbon rods well before moving to the next beaker.

Figure to be added

The test circuit: a beaker of solution with two carbon rods standing in it, wired through a bulb to a battery (figure 10.21).

What is observed

Beaker Contents Bulb
A Common salt solution Lights
B Copper sulfate solution Lights
C Sugar solution Does not light
D Distilled water Does not light

Reading the result

Common salt and copper sulfate are ionic compounds; sugar and water are covalent. So the compounds that conducted are exactly the ionic ones.

A current is a flow of charge, and it needs charged particles free to move. Dissolving an ionic compound releases its ions into the water, where they can travel. A covalent compound dissolves as whole, uncharged molecules, and there is nothing for the current to move.

Solid, molten, dissolved

Experiment has also shown that molten common salt conducts. But an ionic compound in the solid state does not — and the reason is the lattice.

State of an ionic compound Can the ions move? Conducts?
Solid No, they are locked in the lattice No
Molten Yes, the lattice has broken down Yes
Dissolved in water Yes, the ions are free in solution Yes

Having ions is not enough

Solid salt is made entirely of ions and still does not conduct. What a current needs is charged particles that are free to move, and in the lattice they are held fast.