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Lesson: Chapter 10 — Chemical Bonds

10.1. Ionic bonds 3 of 5

How sodium chloride forms

Sodium has an electron it does not want. Chlorine wants exactly one electron. Put the two together and the transfer happens.

Before and after

Sodium Chlorine
Before combining Na atom · 11 protons · 11 electrons (2, 8, 1) Cl atom · 17 protons · 17 electrons (2, 8, 7)
After combining Na+ ion · 11 protons · 10 electrons (2, 8) Cl− ion · 17 protons · 18 electrons (2, 8, 8)

One electron has moved and nothing else. Both particles now have a full outer shell, and both are charged — one positively, one negatively.

What holds them together

Opposite charges attract. The Na+ and Cl− ions are drawn to each other strongly, and that attraction is the bond. Nothing else is needed: no shared electrons, no further reaction, just electrostatic attraction between two oppositely charged particles.

Figure to be added

The sodium ion and the chloride ion drawn side by side in brackets, marked + and −, with the attraction between them (figure 10.5).

Ionic bond

The bond formed by the strong electrostatic attraction between the positive and negative ions that result when one atom donates electrons to another. It is also called an electrovalent bond.

transfer of electrons → opposite charges → attraction

Sodium chloride is therefore a compound made of ionic bonds, and compounds of this kind are called ionic compounds.

An ionic bond is not a new kind of force. It is ordinary electrostatic attraction, doing its ordinary job, between particles that a transferred electron has left charged.