Mass fraction
The first way of stating a composition, and the simplest: weigh the component, weigh the whole thing, divide.
Mass fraction of A
mass of A ÷ (mass of A + mass of B)
that is, mass of A ÷ total mass of the mixture
The mass fraction of a component of a mixture is the ratio its mass bears to the total mass of the mixture. It is a ratio of two masses, so it has no units.
Example 1 — a solute in 100 g of solution
Problem
A solution of 100 g contains 5 g of solute. Express the composition of the solute in it as a mass fraction.
Solution
mass fraction of solute = mass of solute ÷ mass of solution
= 5 g ÷ 100 g
= 1 ÷ 20
= 0.05
Example 2 — evaporating a salt solution
Problem
250 g of a salt (NaCl) solution is measured out accurately, and when all the water in it is evaporated off, 10 g of salt is obtained. Give the composition of the salt in this solution as a mass fraction.
Solution
mass fraction of salt = 10 g ÷ 250 g
= 1 ÷ 25
= 0.04
Evaporating the water is what makes the mass of solute measurable. The 250 g was the whole solution, water included.
A check worth doing
A mass fraction can never come out greater than 1, because the part can never be heavier than the whole. An answer above 1 means the division went the wrong way round.